Biodiesel is an eco-friendly, alternative diesel fuel prepared from domestic renewable resources i.e. mainly produced from vegetable oils and animal fats. It is a renewable energy source that appears to be the perfect answer to the world's energy needs, especially those of Ethiopia. The aim of present study was to evaluate the physicochemical characterization and production of biodiesel from cottonseed oil and waste cooking oil. Transesterification of edible and non-edible oil with methanol in the presence of strong acid or base catalysts is the standard process for creating biodiesel. The percent yield of cottonseed crude oil was found to be 62.98 % upon the extraction from the cotton seeds. After food residues and sediments were removed using chemical coagulation with 2% Al2SO4 as a coagulating agent and gravitational sedimentation, approximately 90.24 percent of the oil was recovered. The physicochemical parameters of oils and its biodiesel were performed and the experimental results such as moisture content (0.32% and 0.27%), specific gravity (0.86-0.9258), viscosity (4.1-65mm2/sec), saponification value (56.1-182.3 mg/g), Iodine value (51.74-120.53 mgI2/g), Acid value (0.30-0.50 mg/g), free fatty acid content ¬¬¬(0.23-1.9%), cetane number (74.6-137.56) and higher heat values (40.87-48.94 MJ/kg) are good agreement with ASTM standards. In conclusion, the result of recent study confirmed that the cottonseed oil and waste cooking oil derived biodiesel is an alternative renewable biofuel for petro-diesel with an eco-friendly.
Published in | International Journal of Sustainable and Green Energy (Volume 13, Issue 4) |
DOI | 10.11648/j.ijrse.20241304.12 |
Page(s) | 82-89 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Biodiesel, Cottonseed Oil, Saponification, Transesterification, Waste Cooking Oil
[1] | Balat, M. and Balat, H., Recent trends in global production and utilization of bio-ethanol fuel. Applied energy, 86(11), pp. 2273-2282, 2009. |
[2] | Ozturk, H. H., Energy analysis for biodiesel production from rapeseed oil. Energy exploration & exploitation, 32(6), pp. 1005-1031, 2014. |
[3] | Gopal, B. V., Sridevi, V., Sarma, A. J. N. and Rao, P. V., Processing and Characterization of cotton seed methyl ester. Austin Chem Eng, 2(2), pp. 1-6, 2015. |
[4] | Samir, Abd-elmonem.; A Ismail.; Rehab. Farouk. M Ali.; physico-chemical properties of biodiesel manufactured from waste frying oil using domestic adsorbents. Science Technology Advance Mater., 16, 034602, 2015. |
[5] | Kayode Ebenezer Samuel.; physicochemical characterisation of the oil extract from the seed of umbrella tree (terminalia mentalis). International Journal of Scientific and Engineering; 6, 2229-5518, 2015. |
[6] | Da Silva Filho, S. C.; Miranda, A. C.; Silva, T. A. F.; Calarge, F. A.; de Souza, R. R.; Santana, J. C. C.; Tambourgi, E. B.; Environmental and techno-economic considerations on biodiesel production from waste frying oil in São Paulo city. J. Clean. Prod., 183, 1034–1042, 2018. |
[7] | Du Ploy, J.; Nel. R.; A study of a feebate policy aimed at vehicle manufacturers to reduce CO2 emissions. International Business and Economics Research;, 11, 1029–1040. 2012. |
[8] | Ghiaci, M.; Aghabarari, B.; Gil, A.; Production of biodiesel by esterification of natural fatty acids over modified organoclay catalysts. Fuel., 90, 3382–3389. 2011. |
[9] | Hayyan, M.; Mjalli, F. S.; Hashim, M. A.; AlNashef, I. M.; A novel technique for separating glycerine from palm oil-based biodiesel using ionic liquids. Fuel Process. Technol.; 91, 116–120. 2010. |
[10] | Ren, Q.; Zuo, T.; Pan, J.; Chen, C.; Li, W.; Preparation of biodiesel from soybean catalyzed by basic ionic liquids OH. Materials, 7, 8012–8023, 2014. |
[11] | Kemausuor, F.; Akowuah, J. O.; Ofori, E.; Assessment of feedstock options for biofuels productionin Ghana. Journal of Sustainable Bioenergy Systems.; 3, 1–10. 2013 |
[12] | Thirumurugaveerakumar S1, Raghul S2, Sam Vimal Kumar S 3, Ajay R, Production and Property Analysis of Biodiesel from Cotton Seed Oil Using Natural Catalyst, International Journal of Applied Engineering Research, Volume 13, pp. 5672-5679. 2018. |
[13] | Wang, R.; Zhou, W.-W.; Hanna, M. A.; Zhang, Y.-P.; Bhadury, P. S.; Wang, Y.; Song, B.-A.; Yang, S.; Biodiesel preparation, optimization, and fuel properties from non-edible feedstock, Daturastramonium L. Fuel.;, 91, 182–186. 2012. |
[14] | Figiel, S.; Hamulczuk, M.; The effects of increase in production of biofuels on world agricultural prices and food security. European Scientific Journal. 9, 10–17. 2014. |
[15] | Yucel, Y. Optimization of biocatalytic biodiesel production from pomace oil using response surface methodology. Fuel Process. Technol.; 99, 97–102. 2012. |
[16] | Ge, J. C.; Kim, H. Y.; Yoon, S. K.; Choi, N. J.; Reducing volatile organic compound emissions from diesel engines using canola oil biodiesel fuel and blends. Fuel., 218, 266–274. 2018. |
[17] | Van Gerpen, JH; Peterson, CL.; Goering, CE. Biodiesel: An Alternative Fuel for Compression Ignition Engines, for presentation at the Agricultural Equipment Technology Conference Louisville, Kentucky, USA. 2007. |
[18] | Rahman, KM.; Mohammad, M.; Asadullah, AG.; Roknuzzaman, M.; ‘Biodiesel from Jatropha oil as an alternative fuel for diesel engine. 10, 1-6. 2009. |
[19] | Al Basir, F.; Datta, S.; Roy, PK.; “Studies on biodiesel production from JatrophaCurcas oil using chemical and biochemical methods. A mathematical approach, Fuel” 158, 503- 511. 2015. |
[20] | Joshi, HC.; Toler, J.; Walker, T.; “Optimization of Cotton seed oil ethanolysis to produce biodiesel high in Gossypol content,” JAOCS, J. Am. Oil Chem. Soc, 85(4) 357–363. 2008. |
[21] | Bankovic, IB.; Stamenkoviv, OS.; Veljkovic, VB.; “Biodiesel production from non-edible plant oils.” Renew. Sustain. Energy Rev, 16, 3621–3647; 2012. |
[22] | Ribeiro, A.; Castro, F.; Carvalho, J.; “Influence of Free Fatty Acid Content in Biodiesel Production on Non-Edible Oils.” in International Conference Waste: Solutions, Treatments and Opportunities; 2011. |
[23] | Dominic Okechukwu Onukwuli a, Lovet Nwanneka Emembolu a, Callistus Nonso Ude b, Sandra Ogechukwu Aliozo a, Mathew Chukwudi Menkiti, Optimization of biodiesel production from refined cotton seed oil and its characterization, Egyptian Journal of Petroleum, 2016. |
[24] | Balewu, MA.; Adekola, FA.; Adebayo, GB.; Ameen, OM.; Mohammed, NO.; Olaniyan, AM.; Adekola, OF.; Musa, AK.; Physicochemical characteristics of oil and biodiesel from Nigerian and Indian Jatrophacurcas seeds. International Journal of Biological and Chemical Sciences. 4: 524-529. 2010 |
[25] | Verma, KC.; Juneja, N.; International Journal of Sustainable Energy.; 33, 946–953. 2014. |
[26] | Ribeiro A, Castro F, and CarvalhoJ, “Influence of Free Fatty Acid Content in Biodiesel Production on Non-Edible Oils,” in International Conference Waste: Solutions, Treatments and Opportunities. 2011. |
APA Style
Tilinti, B. Z., Tura, A. M., Tsegaye, K., Desta, E., Jihad, H. (2024). Physicochemical Characterization and Production of Biodiesel from Cottonseed Oil and Waste Cooking Oil. International Journal of Sustainable and Green Energy, 13(4), 82-89. https://doi.org/10.11648/j.ijrse.20241304.12
ACS Style
Tilinti, B. Z.; Tura, A. M.; Tsegaye, K.; Desta, E.; Jihad, H. Physicochemical Characterization and Production of Biodiesel from Cottonseed Oil and Waste Cooking Oil. Int. J. Sustain. Green Energy 2024, 13(4), 82-89. doi: 10.11648/j.ijrse.20241304.12
@article{10.11648/j.ijrse.20241304.12, author = {Birhanu Zeleke Tilinti and Alemu Mekonnen Tura and Kasahun Tsegaye and Etalem Desta and Hawi Jihad}, title = {Physicochemical Characterization and Production of Biodiesel from Cottonseed Oil and Waste Cooking Oil }, journal = {International Journal of Sustainable and Green Energy}, volume = {13}, number = {4}, pages = {82-89}, doi = {10.11648/j.ijrse.20241304.12}, url = {https://doi.org/10.11648/j.ijrse.20241304.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijrse.20241304.12}, abstract = {Biodiesel is an eco-friendly, alternative diesel fuel prepared from domestic renewable resources i.e. mainly produced from vegetable oils and animal fats. It is a renewable energy source that appears to be the perfect answer to the world's energy needs, especially those of Ethiopia. The aim of present study was to evaluate the physicochemical characterization and production of biodiesel from cottonseed oil and waste cooking oil. Transesterification of edible and non-edible oil with methanol in the presence of strong acid or base catalysts is the standard process for creating biodiesel. The percent yield of cottonseed crude oil was found to be 62.98 % upon the extraction from the cotton seeds. After food residues and sediments were removed using chemical coagulation with 2% Al2SO4 as a coagulating agent and gravitational sedimentation, approximately 90.24 percent of the oil was recovered. The physicochemical parameters of oils and its biodiesel were performed and the experimental results such as moisture content (0.32% and 0.27%), specific gravity (0.86-0.9258), viscosity (4.1-65mm2/sec), saponification value (56.1-182.3 mg/g), Iodine value (51.74-120.53 mgI2/g), Acid value (0.30-0.50 mg/g), free fatty acid content ¬¬¬(0.23-1.9%), cetane number (74.6-137.56) and higher heat values (40.87-48.94 MJ/kg) are good agreement with ASTM standards. In conclusion, the result of recent study confirmed that the cottonseed oil and waste cooking oil derived biodiesel is an alternative renewable biofuel for petro-diesel with an eco-friendly. }, year = {2024} }
TY - JOUR T1 - Physicochemical Characterization and Production of Biodiesel from Cottonseed Oil and Waste Cooking Oil AU - Birhanu Zeleke Tilinti AU - Alemu Mekonnen Tura AU - Kasahun Tsegaye AU - Etalem Desta AU - Hawi Jihad Y1 - 2024/11/22 PY - 2024 N1 - https://doi.org/10.11648/j.ijrse.20241304.12 DO - 10.11648/j.ijrse.20241304.12 T2 - International Journal of Sustainable and Green Energy JF - International Journal of Sustainable and Green Energy JO - International Journal of Sustainable and Green Energy SP - 82 EP - 89 PB - Science Publishing Group SN - 2575-1549 UR - https://doi.org/10.11648/j.ijrse.20241304.12 AB - Biodiesel is an eco-friendly, alternative diesel fuel prepared from domestic renewable resources i.e. mainly produced from vegetable oils and animal fats. It is a renewable energy source that appears to be the perfect answer to the world's energy needs, especially those of Ethiopia. The aim of present study was to evaluate the physicochemical characterization and production of biodiesel from cottonseed oil and waste cooking oil. Transesterification of edible and non-edible oil with methanol in the presence of strong acid or base catalysts is the standard process for creating biodiesel. The percent yield of cottonseed crude oil was found to be 62.98 % upon the extraction from the cotton seeds. After food residues and sediments were removed using chemical coagulation with 2% Al2SO4 as a coagulating agent and gravitational sedimentation, approximately 90.24 percent of the oil was recovered. The physicochemical parameters of oils and its biodiesel were performed and the experimental results such as moisture content (0.32% and 0.27%), specific gravity (0.86-0.9258), viscosity (4.1-65mm2/sec), saponification value (56.1-182.3 mg/g), Iodine value (51.74-120.53 mgI2/g), Acid value (0.30-0.50 mg/g), free fatty acid content ¬¬¬(0.23-1.9%), cetane number (74.6-137.56) and higher heat values (40.87-48.94 MJ/kg) are good agreement with ASTM standards. In conclusion, the result of recent study confirmed that the cottonseed oil and waste cooking oil derived biodiesel is an alternative renewable biofuel for petro-diesel with an eco-friendly. VL - 13 IS - 4 ER -